Solid-state hydrolysis of cellulose and methyl α- and β-d-glucopyranosides in presence of magnesium chloride

Shimada, Naoki; Kawamoto, Haruo; Saka, Shiro

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http://hdl.handle.net/2433/240767

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DCフィールド	値	言語
dc.contributor.author	Shimada, Naoki	en
dc.contributor.author	Kawamoto, Haruo	en
dc.contributor.author	Saka, Shiro	en
dc.contributor.alternative	島田, 有樹	ja
dc.contributor.alternative	河本, 晴雄	ja
dc.contributor.alternative	坂, 志朗	ja
dc.date.accessioned	2019-04-09T07:46:45Z	-
dc.date.available	2019-04-09T07:46:45Z	-
dc.date.issued	2007-07-23	-
dc.identifier.issn	0008-6215	-
dc.identifier.issn	1873-426X	-
dc.identifier.uri	http://hdl.handle.net/2433/240767	-
dc.description.abstract	Solid-state hydrolysis proceeded with cellulose and methyl α- and β-d-glucopyranosides in the presence of hydrated magnesium chloride. This reaction was effective even at >100 °C since the hydrated water, which is held by MgCl₂ up to >200 °C, is utilized as a nucleophile. Excess water made this reaction ineffective due to the competition between water and sugar oxygen atoms in coordinating with Mg²⁺, a Lewis acid. Consequently, this hydrolysis reaction is characteristic of solid-state reactions.	en
dc.language.iso	eng	-
dc.publisher	Elsevier BV	en
dc.rights	© 2007. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/	en
dc.rights	The full-text file will be made open to the public on 23 July 2009 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.	en
dc.rights	This is not the published version. Please cite only the published version.	en
dc.rights	この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。	ja
dc.subject	Cellulose	en
dc.subject	Magnesium chloride	en
dc.subject	Hydrolysis	en
dc.subject	Solid-state hydrolysis	en
dc.subject	Methyl α- and β-d-Glucopyranosides	en
dc.subject	Lewis acid	en
dc.title	Solid-state hydrolysis of cellulose and methyl α- and β-d-glucopyranosides in presence of magnesium chloride	en
dc.type	journal article	-
dc.type.niitype	Journal Article	-
dc.identifier.ncid	AA00598932	-
dc.identifier.jtitle	Carbohydrate Research	en
dc.identifier.volume	342	-
dc.identifier.issue	10	-
dc.identifier.spage	1373	-
dc.identifier.epage	1377	-
dc.relation.doi	10.1016/j.carres.2007.04.009	-
dc.textversion	author	-
dc.address	Graduate School of Energy Science, Kyoto University	en
dc.address	Graduate School of Energy Science, Kyoto University	en
dc.address	Graduate School of Energy Science, Kyoto University	en
dc.identifier.pmid	17498675	-
dcterms.accessRights	open access	-
datacite.date.available	2009-07-23	-
dc.identifier.pissn	0008-6215	-
dc.identifier.eissn	1873-426X	-
出現コレクション:	学術雑誌掲載論文等

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