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dc.contributor.authorKawamoto, H.en
dc.contributor.authorSaka, S.en
dc.contributor.alternative河本, 晴雄ja
dc.contributor.alternative坂, 志朗ja
dc.date.accessioned2019-04-10T05:05:59Z-
dc.date.available2019-04-10T05:05:59Z-
dc.date.issued2006-06-
dc.identifier.issn0165-2370-
dc.identifier.urihttp://hdl.handle.net/2433/240782-
dc.description.abstractIn sulfolane (tetramethylene sulfone), which is a good solvent for the primary product, levoglucosan, cellulose is pyrolyzed completely into soluble products without forming any char. Residues during pyrolysis in sulfolane at 200, 240 and 330 °C were obtained always as colorless non-carbonized substances. From the change in the crystallinity and crystallite size as compared with the ordinary pyrolysis, a heterogeneous mechanism is indicated for cellulose pyrolysis, starting from a molecule which is less stabilized due to lack of some intermolecular interactions.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherElsevier BVen
dc.rights© 2006. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.rightsThe full-text file will be made open to the public on 1 June 2008 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsThis is not the published version. Please cite only the published version.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.subjectCelluloseen
dc.subjectPyrolysisen
dc.subjectMechanismen
dc.subjectHeterogeneousen
dc.subjectCrystallineen
dc.subjectNon-crystallineen
dc.subjectSulfolaneen
dc.titleHeterogeneity in cellulose pyrolysis indicated from the pyrolysis in sulfolaneen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.ncidAA00256768-
dc.identifier.jtitleJournal of Analytical and Applied Pyrolysisen
dc.identifier.volume76-
dc.identifier.issue1-2-
dc.identifier.spage280-
dc.identifier.epage284-
dc.relation.doi10.1016/j.jaap.2005.12.011-
dc.textversionauthor-
dc.addressGraduate School of Energy Science, Kyoto Universityen
dc.addressGraduate School of Energy Science, Kyoto Universityen
dcterms.accessRightsopen access-
datacite.date.available2008-06-01-
datacite.awardNumber16580132-
dc.identifier.pissn0165-2370-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
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