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dc.contributor.authorKawamoto, Haruoen
dc.contributor.authorMurayama, Masaruen
dc.contributor.authorSaka, Shiroen
dc.contributor.alternative河本, 晴雄ja
dc.contributor.alternative村山, 勝ja
dc.contributor.alternative坂, 志朗ja
dc.date.accessioned2019-04-10T05:49:13Z-
dc.date.available2019-04-10T05:49:13Z-
dc.date.issued2003-10-
dc.identifier.issn1435-0211-
dc.identifier.issn1611-4663-
dc.identifier.urihttp://hdl.handle.net/2433/240783-
dc.descriptionPart of this study was presented at the XIXth International Carbohydrate Symposium, San Diego, August 1998; and the 50th Annual Meeting of the Japan Wood Research Society, Kyoto, April 2000en
dc.description.abstractPyrolysis behavior of levoglucosan (1, 6-anhydro-β-d-glucopyranose), the major anhydromonosaccharide formed during cellulose pyrolysis, was studied at 250°–400°C under nitrogen. The pyrolysis products were found to change stepwise: levoglucosan → MeOH-soluble fraction (lower-molecular-weight products and oligosaccharides) → water-soluble fraction (polysaccharides) → insoluble fraction (carbonized products). From the present experimental results, a pathway of cellulose pyrolysis via anhydromonosaccharide is proposed including polymerization to polysaccharides (a reversible reaction) as a key reaction to carbonized product formation.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherSpringerOpenen
dc.rights© The Japan Wood Research Society 2003en
dc.rightsThis is an open access article.en
dc.subjectPyrolysis mechanismen
dc.subjectCelluloseen
dc.subjectLevoglu-cosanen
dc.subjectPolymerizationen
dc.subjectCarbonizationen
dc.titlePyrolysis behavior of levoglucosan as an intermediate in cellulose pyrolysis: polymerization into polysaccharide as a key reaction to carbonized product formationen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleJournal of Wood Scienceen
dc.identifier.volume49-
dc.identifier.spage469-
dc.identifier.epage473-
dc.relation.doi10.1007/s10086-002-0487-5-
dc.textversionpublisher-
dc.identifier.artnum487-
dc.addressDepartment of Socio-Environmental Energy Science, Graduate School of Energy Science, Kyoto Universityen
dc.addressDepartment of Socio-Environmental Energy Science, Graduate School of Energy Science, Kyoto Universityen
dc.addressDepartment of Socio-Environmental Energy Science, Graduate School of Energy Science, Kyoto Universityen
dcterms.accessRightsopen access-
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