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dc.contributor.author | Yamamoto, Masanori | en |
dc.contributor.author | Obara, Miyuki | en |
dc.contributor.author | Ochi, Keisuke | en |
dc.contributor.author | Yamamoto, Atsushi | en |
dc.contributor.author | Takenaka, Katsuhiko | en |
dc.contributor.author | Tanaka, Tsunehiro | en |
dc.contributor.author | Sato, Kazunori | en |
dc.contributor.alternative | 田中, 庸裕 | ja |
dc.date.accessioned | 2020-03-30T07:48:25Z | - |
dc.date.available | 2020-03-30T07:48:25Z | - |
dc.date.issued | 2018-09 | - |
dc.identifier.issn | 2192-6506 | - |
dc.identifier.uri | http://hdl.handle.net/2433/250001 | - |
dc.description.abstract | The associative interaction between resin‐bound polybrominated arenes and small molecules was analyzed by using various spectroscopic techniques as well as a synthetic molecular model to establish the thermodynamics. The binding in acetonitrile was three orders of magnitude stronger than that in methanol, partly owing to the tertiary conformational gating of the resin that controls the entropic terms. By using the entropic superiority, the associative binding of up to 3×104 m−1 is achieved with the non‐biological system. A modified Hill plot for the quantitative analysis of bindings was also devised, which enabled the interactions at the molecular level to be elucidated. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley | en |
dc.rights | © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. | en |
dc.subject | adsorption | en |
dc.subject | entropy | en |
dc.subject | liquid chromatography | en |
dc.subject | noncovalent interactions | en |
dc.subject | solid-phase extraction | en |
dc.title | Probing the Entropic Effect in Molecular Noncovalent Interactions between Resin-Bound Polybrominated Arenes and Small Substrates | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | ChemPlusChem | en |
dc.identifier.volume | 83 | - |
dc.identifier.issue | 9 | - |
dc.identifier.spage | 820 | - |
dc.identifier.epage | 824 | - |
dc.relation.doi | 10.1002/cplu.201800304 | - |
dc.textversion | publisher | - |
dc.identifier.pmid | 31950680 | - |
dcterms.accessRights | open access | - |
datacite.awardNumber | 17H06702 | - |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
出現コレクション: | 学術雑誌掲載論文等 |
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