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タイトル: | Predicting Solid–Liquid Equilibrium of Fatty Acid Methyl Ester and Monoglyceride Mixtures as Biodiesel Model Fuels |
著者: | Yoshidomi, Shinichiro Sugami, Yuitsu Minami, Eiji https://orcid.org/0000-0001-7434-2968 (unconfirmed) Shisa, Noriko Hayashi, Hitoshi Saka, Shiro |
著者名の別形: | 南, 英治 坂, 志朗 |
キーワード: | Biodiesel Solid–liquid equilibrium Fatty acid methyl ester Monoglyceride |
発行日: | Aug-2017 |
出版者: | Wiley |
誌名: | Journal of the American Oil Chemists' Society |
巻: | 94 |
号: | 8 |
開始ページ: | 1087 |
終了ページ: | 1094 |
抄録: | Fatty acid methyl esters from plant oils are the main component of biodiesel and used as a substitute for petroleum diesel. Biodiesel generally contains a small amount of monoglycerides as intermediate compounds, which have high melting points and often solidify and clog fuel filters. The prediction of the cold‐flow property of biodiesel is of great importance for practical application. In this study, a thermodynamic study was conducted for mixtures of monoglycerides and fatty acid methyl esters. Temperatures of the solid–liquid equilibrium for the mixtures were measured by differential scanning calorimetry and visual observation, while the theoretical values were calculated using the modified Universal Quasi‐chemical Functional‐group Activity Coefficients (UNIFAC) model (Dortmund). The theoretical and experimental results were in good agreement, especially for binary mixtures of monoglycerides and methyl esters. The importance of monoglycerides on the cold‐flow properties of biodiesel was determined, and the effects could be well described by the modified UNIFAC model (Dortmund). |
記述: | An erratum to this article is available at https://doi.org/10.1007/s11746‐017‐3029‐4. |
著作権等: | This is the peer reviewed version of the following article: Yoshidomi, S., Sugami, Y., Minami, E., Shisa, N., Hayashi, H. and Saka, S. (2017), Predicting Solid–Liquid Equilibrium of Fatty Acid Methyl Ester and Monoglyceride Mixtures as Biodiesel Model Fuels. J Am Oil Chem Soc, 94: 1087-1094, which has been published in final form at https://doi.org/10.1007/s11746-017-3015-x. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/250159 |
DOI(出版社版): | 10.1007/s11746-017-3015-x |
関連リンク: | https://doi.org/10.1007/s11746‐017‐3029‐4 |
出現コレクション: | 学術雑誌掲載論文等 |
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