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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| 1.1795613.pdf | 281.99 kB | Adobe PDF | 見る/開く |
| タイトル: | Room-Temperature Ionic Liquids with High Conductivities and Wide Electrochemical Windows |
| 著者: | Matsumoto, Kazuhiko    https://orcid.org/0000-0002-0770-9210 (unconfirmed)Hagiwara, Rika https://orcid.org/0000-0002-7234-3980 (unconfirmed)Ito, Yasuhiko |
| 著者名の別形: | 松本, 一彦 萩原, 理加 伊藤, 靖彦 |
| 発行日: | 2004 |
| 出版者: | The Electrochemical Society |
| 誌名: | Electrochemical and Solid-State Letters |
| 巻: | 7 |
| 号: | 10 |
| 論文番号: | E41 |
| 抄録: | Room-temperature ionic liquids (RTILs), N-alkyl-N-methylpyrrolidinium (RMPyr⁺) and N-alkyl-N-methylpiperidinium (RMPip⁺) fluorohydrogenates formulated by RMPyr( HF )₂.₃F and RMPip( HF )₂.₃F ( R = ethyl, propyl, and butyl), have been synthesized by the reactions of the corresponding chlorides and anhydrous hydrogen fluoride. These RTILs exhibit relatively low viscosities (11.5-34.4 cP), high conductivities (12.3-74.6 mS cm⁻¹), and wide electrochemical widows around 5 V using glassy carbon electrodes. The fluorohydrogenate salts of symmetric cations, N, N-dimethylpyrrolidinium (DMPyr⁺) and N, N-dimethylpiperidinium (DMPip⁺) obtained by evacuation at room temperature are solids, exhibiting the composition of DMPyrF-2HF and DMPipF-2HF. |
| 著作権等: | This is the Accepted Manuscript version of an article accepted for publication in Electrochemical and Solid-State Letters. IOP Publishing Ltd is not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at https://doi.org/10.1149/1.1795613. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/254681 |
| DOI(出版社版): | 10.1149/1.1795613 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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