ダウンロード数: 216
このアイテムのファイル:
ファイル | 記述 | サイズ | フォーマット | |
---|---|---|---|---|
acsami.0c17807.pdf | 1.39 MB | Adobe PDF | 見る/開く |
タイトル: | Improvement of Electrochemical Stability Using the Eutectic Composition of a Ternary Molten Salt System for Highly Concentrated Electrolytes for Na-Ion Batteries |
著者: | Hwang, Jinkwang https://orcid.org/0000-0003-4800-3158 (unconfirmed) Sivasengaran, Nair, Ashvini Yang, Huan Yamamoto, Hiroki https://orcid.org/0000-0002-7234-3980 (unconfirmed) Takeuchi, Takashi Matsumoto, Kazuhiko https://orcid.org/0000-0002-0770-9210 (unconfirmed) Hagiwara, Rika https://orcid.org/0000-0002-7234-3980 (unconfirmed) |
著者名の別形: | 黄, 珍光 山本, 大樹 松本, 一彦 萩原, 理加 |
キーワード: | sodium-ion batteries electrolytes molten salt highly concentrated electrolytes hard carbon NaCrO₂ |
発行日: | 20-Jan-2021 |
出版者: | American Chemical Society (ACS) |
誌名: | ACS Applied Materials & Interfaces |
巻: | 13 |
号: | 2 |
開始ページ: | 2538 |
終了ページ: | 2546 |
抄録: | The increase in the concentration of electrolytes for secondary batteries has significant advantages in terms of physicochemical and electrochemical performance. This study aims to explore a highly concentrated electrolyte for Na-ion batteries using a ternary salt system. The eutectic composition of the Na[N(SO₂F₂]–Na[N(SO₂F)(SO₂CF₃)]–Na[SO₃CF₃] ternary molten salt system increases solubility into an organic solvent, enabling the use of highly concentrated electrolytes for Na-ion batteries. The ternary salt system achieved concentrations of 5.0 m (m = mol kg⁻¹) with propylene carbonate (PC), 2.9 m with dimethoxyethane, 2.0 m with ethylene carbonate/dimethyl carbonate, and 3.9 m with ethylene carbonate/diethyl carbonate. The highly concentrated electrolyte of 5.0 m in PC suppressed Al corrosion and exhibited better oxidative stability. Stable electrochemical performance using hard carbon/NaCrO₂ in the full-cell configuration introduces a new strategy to explore highly concentrated electrolytes for secondary batteries. |
著作権等: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Materials & Interfaces, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acsami.0c17807. The full-text file will be made open to the public on 5 January 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/261217 |
DOI(出版社版): | 10.1021/acsami.0c17807 |
PubMed ID: | 33400498 |
出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。