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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.orglett.0c03816.pdf | 797.15 kB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Kurose, Tomohiro | en |
| dc.contributor.author | Tsukano, Chihiro | en |
| dc.contributor.author | Nanjo, Takeshi | en |
| dc.contributor.author | Takemoto, Yoshiji | en |
| dc.contributor.alternative | 黒瀬, 朋浩 | ja |
| dc.contributor.alternative | 塚野, 千尋 | ja |
| dc.contributor.alternative | 南條, 毅 | ja |
| dc.contributor.alternative | 竹本, 佳司 | ja |
| dc.date.accessioned | 2021-12-16T08:15:08Z | - |
| dc.date.available | 2021-12-16T08:15:08Z | - |
| dc.date.issued | 2021-02 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/266607 | - |
| dc.description.abstract | This report describes the total synthesis of the complex, oxygenated tetracyclic alkaloid, lyconesidine B. The key synthetic challenge involves diastereoselective generation of a decahydroquinoline ring with a quaternary carbon at the angular position via domino cyclopropanation, ring-opening, and reduction. Another crucial step is the domino ene-yne metathesis involving a quaternary ammonium ion, leading to the construction of a decahydroazaazulen framework. | en |
| dc.language.iso | eng | - |
| dc.publisher | American Chemical Society (ACS) | en |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.0c03816. | en |
| dc.rights | The full-text file will be made open to the public on December 16, 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
| dc.rights | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | en |
| dc.subject | Catalysts | en |
| dc.subject | Organic synthesis | en |
| dc.subject | Organic compounds | en |
| dc.subject | Cyclization | en |
| dc.subject | Chemical synthesis | en |
| dc.title | Total Synthesis of Lyconesidine B, a Lycopodium Alkaloid with an Oxygenated, Amine-Type Fawcettimine Core | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Organic Letters | en |
| dc.identifier.volume | 23 | - |
| dc.identifier.issue | 3 | - |
| dc.identifier.spage | 676 | - |
| dc.identifier.epage | 681 | - |
| dc.relation.doi | 10.1021/acs.orglett.0c03816 | - |
| dc.textversion | author | - |
| dc.identifier.pmid | 33325708 | - |
| dcterms.accessRights | open access | - |
| datacite.date.available | 2021-12-16 | - |
| datacite.awardNumber | 17H05051 | - |
| datacite.awardNumber | 18H04407 | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17H05051/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-18H04407/ | - |
| dc.identifier.pissn | 1523-7060 | - |
| dc.identifier.eissn | 1523-7052 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.awardTitle | 不飽和三員環の自在変換で拓く特異および複雑骨格構築法と全合成的発展 | ja |
| jpcoar.awardTitle | 新規中分子医薬品シード創製を指向した脂肪酸を持つリポヌクレオシド系天然物の全合成 | ja |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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