このアイテムのアクセス数: 245
このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.orglett.1c01355.pdf | 1.32 MB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Fukazawa, Mizuki | en |
| dc.contributor.author | Takahashi, Fumiya | en |
| dc.contributor.author | Yorimitsu, Hideki | en |
| dc.contributor.alternative | 深澤, 瑞喜 | ja |
| dc.contributor.alternative | 高橋, 郁也 | ja |
| dc.contributor.alternative | 依光, 英樹 | ja |
| dc.date.accessioned | 2022-03-10T09:07:08Z | - |
| dc.date.available | 2022-03-10T09:07:08Z | - |
| dc.date.issued | 2021-06 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/268766 | - |
| dc.description.abstract | Sodium dispersion promotes the reductive borylation of polycyclic aromatic hydrocarbons (PAHs) with MeOBpin. Anthracenes and phenanthrenes are converted to the corresponding dearomatized diborylated products. The reductive diborylation of naphthalene-based small π-systems yields similar yet unstable products that are oxidized into formal C–H borylation products with unique regioselectivity. Pyrene is converted to 1-borylpyrene without the addition of an oxidant. The latter two reactions represent a new route to useful borylated PAHs that rivals C–X borylation and catalytic C–H borylation. | en |
| dc.language.iso | eng | - |
| dc.publisher | American Chemical Society (ACS) | en |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, Copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.1c01355. | en |
| dc.rights | The full-text file will be made open to the public on 2 June 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
| dc.rights | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | en |
| dc.subject | Redox reactions | en |
| dc.subject | Hydrocarbons | en |
| dc.subject | Borylation | en |
| dc.subject | Anions | en |
| dc.subject | Aromatic compounds | en |
| dc.subject | reduction | en |
| dc.subject | metalation | en |
| dc.subject | boration | en |
| dc.title | Sodium-Promoted Borylation of Polycyclic Aromatic Hydrocarbons | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Organic Letters | en |
| dc.identifier.volume | 23 | - |
| dc.identifier.issue | 12 | - |
| dc.identifier.spage | 4613 | - |
| dc.identifier.epage | 4617 | - |
| dc.relation.doi | 10.1021/acs.orglett.1c01355 | - |
| dc.textversion | author | - |
| dc.identifier.pmid | 34076437 | - |
| dcterms.accessRights | open access | - |
| datacite.date.available | 2022-06-02 | - |
| datacite.awardNumber | 19H00895 | - |
| datacite.awardNumber | 20J22814 | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-19H00895/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-20J22814/ | - |
| dc.identifier.pissn | 1523-7060 | - |
| dc.identifier.eissn | 1523-7052 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.awardTitle | 芳香環の還元的破壊に基づく有機合成 | ja |
| jpcoar.awardTitle | 不飽和結合への電子移動に基づく有機ホウ素化合物の新規合成法の開発 | ja |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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