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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.orglett.2c00084.pdf | 1.24 MB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Wang, Shuo | en |
| dc.contributor.author | Kaga, Atsushi | en |
| dc.contributor.author | Kurogi, Takashi | en |
| dc.contributor.author | Yorimitsu, Hideki | en |
| dc.contributor.alternative | 王, 爍 | ja |
| dc.contributor.alternative | 加賀, 敦志 | ja |
| dc.contributor.alternative | 黒木, 尭 | ja |
| dc.contributor.alternative | 依光, 英樹 | ja |
| dc.date.accessioned | 2022-03-10T09:07:13Z | - |
| dc.date.available | 2022-03-10T09:07:13Z | - |
| dc.date.issued | 2022-02 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/268767 | - |
| dc.description.abstract | Treatment of arylcyclopropanecarboxamides with a sodium dispersion in the presence of methoxypinacolborane as a reduction-resistant electrophile leads to reductive cleavage of the cyclopropane ring followed by instant trapping with the boron electrophile to yield the enolates of γ-aryl-γ-borylalkanamides. The enolates react further with a different electrophile to yield the corresponding α-substituted amides with anti selectivity. | en |
| dc.language.iso | eng | - |
| dc.publisher | American Chemical Society (ACS) | en |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, Copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.2c00084. | en |
| dc.rights | The full-text file will be made open to the public on 25 January 2023 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
| dc.rights | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | en |
| dc.subject | Enolates | en |
| dc.subject | Ring opening reactions | en |
| dc.subject | Carbonyls | en |
| dc.subject | Electrophiles | en |
| dc.subject | Selectivity | en |
| dc.subject | reduction | en |
| dc.subject | cyclopropane | en |
| dc.subject | metalation | en |
| dc.subject | borylation | en |
| dc.subject | enolate | en |
| dc.title | Reductive Ring Opening of Arylcyclopropanecarboxamides Accompanied by Borylation and Enolate Formation | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Organic Letters | en |
| dc.identifier.volume | 24 | - |
| dc.identifier.issue | 4 | - |
| dc.identifier.spage | 1105 | - |
| dc.identifier.epage | 1109 | - |
| dc.relation.doi | 10.1021/acs.orglett.2c00084 | - |
| dc.textversion | author | - |
| dc.identifier.pmid | 35076241 | - |
| dcterms.accessRights | open access | - |
| datacite.date.available | 2023-01-25 | - |
| datacite.awardNumber | 19H00895 | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-19H00895/ | - |
| dc.identifier.pissn | 1523-7060 | - |
| dc.identifier.eissn | 1523-7052 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.awardTitle | 芳香環の還元的破壊に基づく有機合成 | ja |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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