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タイトル: | Electrochemical Formation of Nd-Fe Alloys in Molten LiF-CaF₂-NdF₃ |
著者: | Kawaguchi, Kenji https://orcid.org/0000-0002-8883-9040 (unconfirmed) Nohira, Toshiyuki https://orcid.org/0000-0002-4053-554X (unconfirmed) |
著者名の別形: | 川口, 健次 野平, 俊之 |
発行日: | Aug-2021 |
出版者: | The Electrochemical Society IOP Publishing |
誌名: | Journal of The Electrochemical Society |
巻: | 168 |
号: | 8 |
論文番号: | 082503 |
抄録: | In the present study, as a fundamental study for recycling Nd from Nd-Fe-B permanent magnet scrap, the electrochemical Nd-alloying behavior of Fe was investigated in a molten LiF-CaF₂-NdF₃ (0.3 or 0.5 mol%) system at 1123 K. Herein, the equilibrium potential of Nd³⁺/Nd was determined as 0.18 V (vs Li⁺/Li) by open-circuit potentiometry using a Mo electrode. Cyclic voltammetry and open-circuit potentiometry were conducted using an Fe electrode, and the results suggested the formation of multiple phases within the Nd-Fe alloys. Alloy samples were prepared via one- or two-step potentiostatic electrolysis of Fe electrodes at various potentials. The formation of liquid Nd-Fe alloy was confirmed through one-step potentiostatic electrolysis at 0.10 V. The solid Nd₂Fe₁₇ alloy was formed via a two-step potentiostatic electrolysis, wherein the potential was changed to 0.25 V after the initial electrolysis at 0.10 V, indicating that the Nd₂Fe₁₇ phase is thermodynamically stable at 0.25 V. The equilibrium potentials of the coexistence states of liq. Nd-Fe + Nd₂Fe₁₇ and Nd₂Fe₁₇ + Fe were determined as 0.19 and 0.31 V, respectively, which are in good agreement with the previously reported thermodynamic data. |
著作権等: | © 2021 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. |
URI: | http://hdl.handle.net/2433/274211 |
DOI(出版社版): | 10.1149/1945-7111/ac180e |
出現コレクション: | 学術雑誌掲載論文等 |
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