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Title: A new method to estimate the intrinsic term in activation and reaction volumes
Authors: Asano, Tsutomu
Issue Date: 20-Feb-1980
Publisher: The Physico-Chemical Society of Japan
Journal title: The Review of Physical Chemistry of Japan
Volume: 49
Issue: 2
Start page: 109
End page: 119
Abstract: A simple formula is proposed to describe the effect of pressure on the rate and equilibrium constant of ionic reactions. The expression, given in Eq. (7), has been applied to known data and shown to provide a good description of the pressure effects on a variety of ionic reactions. The extrapolation of the relation to infinite pressure allows us to estimate the intrinsic volume changes.
URI: http://hdl.handle.net/2433/47084
Appears in Collections:Vol.49 No.2

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