芳香族三塩化アンチモン錯化物 (第2報)

Abstract

The behaviors of benzenediazonium tetrachloroantimonite complex in water and methanol have been reported in the previous paper and as the continuation of the work, the behaviors of the complex in several organic solvents, such as acetone, acetic acid, acetic anhydride, ether and benzene are described in this part. The decomposition products of this complex in acetone, acetic acid and acetic anhydride without catalyst were benzene, chlorobenzene and biphenyl and in the case with Cu or Cu2Cl2 the chief product was phenylstibonic acid. On the occasion of ether with Cu the complex gave a trace of benzene and a large amount of chlorobenzene; in benzene without catalyst it gave chlorobenzene and biphenyl.