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j.apsusc.2016.07.059.pdf | 475 kB | Adobe PDF | 見る/開く |
タイトル: | Electrical resistivity of nanoporous gold modified with thiol self-assembled monolayers |
著者: | Hakamada, Masataka https://orcid.org/0000-0002-8082-2148 (unconfirmed) Kato, Naoki Mabuchi, Mamoru https://orcid.org/0000-0002-0894-6306 (unconfirmed) |
著者名の別形: | 袴田, 昌高 加藤, 直樹 馬渕, 守 |
キーワード: | Nanoporous gold Self-assembled monolayers Thiols Electrical resistivity |
発行日: | 30-Nov-2016 |
出版者: | Elsevier B.V. |
誌名: | Applied Surface Science |
巻: | 387 |
開始ページ: | 1088 |
終了ページ: | 1092 |
抄録: | The electrical resistivity of nanoporous gold (NPG) modified with thiol self-assembled monolayers (SAMs) has been measured at 298 K using a four-probe method. We found that the adsorption of thiol SAMs increases the electrical resistivity of NPG by up to 22.2%. Dependence of the electrical resistivity on the atmosphere (air or water) was also observed in SAMs-modified NPG, suggesting that the electronic states of the tail groups affect the electrons of the binding sulfur and adjacent surface gold atoms. The present results suggest that adsorption of thiol molecules can influence the behavior of the conducting electrons in NPG and that modification of NPG with SAMs may be useful for environmental sensing. |
著作権等: | © 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ The full-text file will be made open to the public on 30 November 2018 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/237624 |
DOI(出版社版): | 10.1016/j.apsusc.2016.07.059 |
出現コレクション: | 学術雑誌掲載論文等 |
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