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Title: Oxygen Electrode Reaction in a LiCl–KCl Eutectic Melt
Authors: Kado, Yuya
Goto, Takuya
Hagiwara, Rika  kyouindb  KAKEN_id  orcid https://orcid.org/0000-0002-7234-3980 (unconfirmed)
Author's alias: 加登, 裕也
後藤, 琢也
萩原, 理加
Issue Date: 2009
Publisher: The Electrochemical Society
Journal title: Journal of The Electrochemical Society
Volume: 156
Thesis number: E167
Abstract: Oxygen electrode reaction was investigated on a boron-doped diamond electrode in a LiCl–KCl eutectic melt. The standard formal potential of O₂/O²⁻ decreases with the elevation of temperature. The potential at 773 K is 2.424 ± 0.003 V vs Li⁺/ Li. The standard formal free energy change increases with the temperature elevation, calculated to be -456.4 ± 0.5 kJ mol⁻¹ at 773 K. The standard formal entropy and enthalpy changes are determined to be -151 ± 3 J K⁻¹ mol⁻¹ and -573.5 ± 0.1 kJ mol⁻¹, respectively, at 773 K.
Rights: This is the Accepted Manuscript version of an article accepted for publication in Journal of The Electrochemical Society. The Electrochemical Society and IOP Publishing Ltd are not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at https://doi.org/10.1149/1.3212844.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
URI: http://hdl.handle.net/2433/255613
DOI(Published Version): 10.1149/1.3212844
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